Magnetic moments and exchange coupling in nitride clusterfullerenes Gd(x)Sc(3-x)N@C80 (x = 1-3).
نویسندگان
چکیده
The magnetic properties of nitride clusterfullerenes GdxSc3-xN@C80 (x = 1-3) are studied as a function of the number of Gd atoms in the cluster. The intracluster interaction of the Gd ions in Gd2ScN@C80 and Gd3N@C80 is ferromagnetic with exchange constants of -1.2 K ± 0.1 K and -0.6 K ± 0.1 K, respectively. At 2 K, the magnetization curves exhibit noticeable deviations from the Heisenberg model pointing to a non-negligible anisotropy.
منابع مشابه
Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc2N@C80-I h with M running through the whole 4f row† †Electronic supplementary information (ESI) available: Details of relaxation time measurements, ligand field splitting, additional correlation between data points, Cartesian coordinates. See DOI: 10.1039/c5sc00154d Click here for additional data file.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 20 شماره
صفحات -
تاریخ انتشار 2014